| 1. Round | 19/08/2024 | Villarreal CF | - | Atlético Madrid | 2:2 | ||||
| 2. Round | 23/08/2024 | Sevilla FC | - | Villarreal CF | 1:2 |  |
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| 3. Round | 26/08/2024 | Villarreal CF | - | RC Celta | 4:3 | ||||
| 4. Round | 31/08/2024 | Valencia CF | - | Villarreal CF | 1:1 | |
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| 5. Round | 14/09/2024 | RCD Mallorca | - | Villarreal CF | 1:2 | |
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| 6. Round | 22/09/2024 | Villarreal CF | - | FC Barcelona | 1:5 | |
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| 7. Round | 26/09/2024 | Espanyol Barcelona | - | Villarreal CF | 1:2 | |
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| 11. Round | 26/10/2024 | Real Valladolid | - | Villarreal CF | 1:2 | |
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| 13. Round | 09/11/2024 | Villarreal CF | - | CD Alavés | 3:0 |
Spain
