| 1. Round | 17/08/2024 | Valencia CF | - | FC Barcelona | 1:2 |  |
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| 2. Round | 24/08/2024 | FC Barcelona | - | Athletic Bilbao | 2:1 | |
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| 3. Round | 27/08/2024 | Rayo Vallecano | - | FC Barcelona | 1:2 | ||||
| 4. Round | 31/08/2024 | FC Barcelona | - | Real Valladolid | 7:0 | |
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| 5. Round | 15/09/2024 | Girona FC | - | FC Barcelona | 1:4 | ||||
| 6. Round | 22/09/2024 | Villarreal CF | - | FC Barcelona | 1:5 | |
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| 7. Round | 25/09/2024 | FC Barcelona | - | Getafe CF | 1:0 | |
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| 8. Round | 28/09/2024 | CA Osasuna | - | FC Barcelona | 4:2 | ||||
| 9. Round | 06/10/2024 | CD Alavés | - | FC Barcelona | 0:3 | |
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| 10. Round | 20/10/2024 | FC Barcelona | - | Sevilla FC | 5:1 | |
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| 11. Round | 26/10/2024 | Real Madrid | - | FC Barcelona | 0:4 | |
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| 12. Round | 03/11/2024 | FC Barcelona | - | Espanyol Barcelona | 3:1 | ||||
| 13. Round | 10/11/2024 | Real Sociedad | - | FC Barcelona | 1:0 |
Poland
